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The thesis explores innovative methods for catalytic C-C bond formation utilizing carboxylate salts via decarboxylation, highlighting the use of iron as a sustainable catalyst. It emphasizes high atom economy and efficient activation of C-H bonds. The work delves into the mechanistic insights of decarboxylative couplings and the reactivity of the iron catalyst, supported by density functional theory calculations, offering a comprehensive understanding of these new catalytic processes.
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New CarbonCarbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed CH Activation, Rui Shang
- Idioma
- Publicado en
- 2016
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